• Medientyp: E-Artikel
  • Titel: A portable transfer chamber for electrochemical measurements on electrodes prepared in ultra-high vacuum
  • Beteiligte: El-Jawad, M.; Chemin, J.-L.; Gilles, B.; Maillard, F.
  • Erschienen: AIP Publishing, 2013
  • Erschienen in: Review of Scientific Instruments
  • Sprache: Englisch
  • DOI: 10.1063/1.4809936
  • ISSN: 1089-7623; 0034-6748
  • Schlagwörter: Instrumentation
  • Entstehung:
  • Anmerkungen:
  • Beschreibung: <jats:p>This paper describes a versatile, light weight, and portable chamber dedicated to the transfer of electrodes from ultra-high vacuum (UHV) to atmospheric pressure and the liquid phase. This chamber can be connected to a liquid-phase reaction cell to perform electrochemical measurements and transfer back the electrode to the UHV environment. The experimental set-up can also be turned in order to make the electrode the bottom of the electrochemical cell. The validity and the efficiency of the experimental set-up were tested with a Pt(111) surface that provides unique electrochemical features in acidic sulphate-containing solution. This transfer chamber concept provides the surface science community with a new and versatile tool, complementary to existing systems, which allows fast electrolyte purging or electrochemical measurements under well-controlled mass transport conditions.</jats:p>