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Medientyp:
E-Artikel
Titel:
Recent advances in catalytic asymmetric dihydroxylation of olefins
Beteiligte:
Ottenbacher, Roman V.;
Talsi, Evgenii P.;
Bryliakov, Konstantin P.
Erschienen:
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 2019
Erschienen in:Russian Chemical Reviews
Sprache:
Nicht zu entscheiden
DOI:
10.1070/rcr4904
ISSN:
0036-021X;
1468-4837
Entstehung:
Anmerkungen:
Beschreibung:
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<jats:p>Asymmetric dihydroxylation of olefinic groups is an extremely important synthetic transformation which has been widely utilized to obtain optically pure pharmaceuticals and other fine chemical products. In recent years, catalyst systems for the asymmetric C=C dihydroxylations have attracted significant interest, the major research efforts being focused on designing environmentally benign catalyst systems. This mini-review summarizes recent progress in the field, surveying both novel, less toxic modifications of the classical osmium-based catalysts, and the highly efficient and enantioselective non-osmium catalyst systems.</jats:p>
<jats:p>The bibliography includes 50 references.</jats:p>