Erschienen in:
Advanced Energy Materials, 5 (2015) 6
Sprache:
Englisch
DOI:
10.1002/aenm.201401660
ISSN:
1614-6832;
1614-6840
Entstehung:
Anmerkungen:
Beschreibung:
<jats:p>An efficient water splitting electrocatalyst is presented. Cheap and sustainable cellulose filter paper, infiltrated with nickel acetate as the nickel source, and phenanthroline as a ligand and nitrogen source are carbonized together. Nitrogen functionalities turn out to be crucial coordination sites for the supported Ni/NiO(OH) particles. This simple and scalable one step procedure leads to powders, but also to complete membranes made of ≈10 wt% Ni, supported on nitrogen functionalized carbon. The non‐noble catalyst shows a low onset potential (330 mV vs reversible hydrogen electrode), high current density (e.g., <jats:italic>j</jats:italic> > 25 mA cm<jats:sup>−2</jats:sup> at <jats:italic>η</jats:italic> = 430 mV), excellent kinetics (Tafel slope of 44 mV dec<jats:sup>−1</jats:sup>), and a very favorable stability (<5% decay after 10 h electrolysis) in the oxygen evolution. The performance is similar or even better compared to state‐of‐the‐art noble metal catalysts (e.g., IrO<jats:sub>2</jats:sub>, Ir/C, Ru/C, and Pt/C). Because of the simple, cheap, and scalable preparation procedure the catalyst is highly promising for practical low price/tech applications. Interestingly, the system is also active in the hydrogen evolution reaction, leading to a promising bifunctional catalyst. The benchmark characteristics are <jats:italic>η</jats:italic><jats:sub>10</jats:sub> = 390 mV for oxygen evolution and <jats:italic>η</jats:italic><jats:sub>10</jats:sub> = 190 mV for hydrogen evolution, that is, an overall efficiency of 68% at 10 mA current density.</jats:p>