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Medientyp:
E-Artikel
Titel:
Negative Capacitance for Electrostatic Supercapacitors
Beteiligte:
Hoffmann, Michael;
Fengler, Franz Paul Gustav;
Max, Benjamin;
Schroeder, Uwe;
Slesazeck, Stefan;
Mikolajick, Thomas
Erschienen:
Wiley, 2019
Erschienen in:Advanced Energy Materials
Sprache:
Englisch
DOI:
10.1002/aenm.201901154
ISSN:
1614-6832;
1614-6840
Entstehung:
Anmerkungen:
Beschreibung:
<jats:title>Abstract</jats:title><jats:p>The increasing demand for efficient storage of electrical energy is one of the main challenges in the transformation toward a carbon neutral society. While electrostatic capacitors can achieve much higher power densities compared to other storage technologies like batteries, their energy densities are comparatively low. Here, it is proposed and demonstrated that negative capacitance, which is present in ferroelectric materials, can be used to improve the energy storage of capacitors beyond fundamental limits. While negative capacitance was previously mainly considered for low power electronics, it is shown that ferroelectric/dielectric capacitors using negative capacitance are promising for energy storage applications. Compared to earlier results using (anti)ferroelectric materials for electrostatic energy storage, much higher efficiencies of more than 95% even for ultrahigh energy densities beyond 100 J cm<jats:sup>−3</jats:sup> are demonstrated using nonepitaxial thin films suitable for integration on 3D substrates. Stable operation up to 150 °C and 10<jats:sup>8</jats:sup> charging/discharging cycles is further demonstrated.</jats:p>