Assessment of fluoroalkyltin compounds as fluorous Lewis acid catalysts

Medientyp: E-Artikel
Titel: Assessment of fluoroalkyltin compounds as fluorous Lewis acid catalysts
Beteiligte: Imakura, Yasuo; Nishiguchi, Satoru; Orita, Akihiro; Otera, Junzo
Erschienen: Wiley, 2003
Erschienen in: Applied Organometallic Chemistry
Sprache: Englisch
DOI: 10.1002/aoc.517
ISSN: 0268-2605; 1099-0739
Schlagwörter: Inorganic Chemistry ; General Chemistry
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Beschreibung: <jats:title>Abstract</jats:title><jats:p>The synthesis of a variety of organotin compounds with 1<jats:italic>H</jats:italic>, 1<jats:italic>H</jats:italic>, 2<jats:italic>H</jats:italic>, 2<jats:italic>H</jats:italic>‐perfluorooctyl groups is reported, together with an improved method for the corresponding distannoxane. Unique properties of this compound are disclosed in terms of fluorophilicity and activity as a Lewis acid catalyst in comparison with other mono‐nuclear derivatives. A new criterion for obtaining high solubility in fluorocarbon solvents is presented. Copyright © 2003 John Wiley & Sons, Ltd.</jats:p>

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