Beck, Wolfgang;
Raab, Klaus;
Nagel, Ulrich;
Sacher, Wolfgang
Pentacarbonylolefin‐ and Pentacarbonyldiolefinrhenium Complex Cations; Synthesis and Structure of the 2‐Butene‐1,4‐diyl‐Bridged Carbonyldirhenium Complex trans‐[(OC)5ReCH2CHCHCH2Re(CO)5]
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Medientyp:
E-Artikel
Titel:
Pentacarbonylolefin‐ and Pentacarbonyldiolefinrhenium Complex Cations; Synthesis and Structure of the 2‐Butene‐1,4‐diyl‐Bridged Carbonyldirhenium Complex trans‐[(OC)5ReCH2CHCHCH2Re(CO)5]
Beteiligte:
Beck, Wolfgang;
Raab, Klaus;
Nagel, Ulrich;
Sacher, Wolfgang
Erschienen:
Wiley, 1985
Erschienen in:Angewandte Chemie International Edition in English
Beschreibung:
<jats:p><jats:bold>Addition of the pentacarbonylrhenate ion to the coordinated olefin</jats:bold> in the complex cation <jats:bold>1</jats:bold> leads to formation of the complex <jats:bold>2</jats:bold>, in which a σ‐η<jats:sup>1</jats:sup>,σ‐η<jats:sup>1</jats:sup>‐type C<jats:sub>4</jats:sub>H<jats:sub>6</jats:sub>‐bridge is realized for the first time. The structure of <jats:bold>2</jats:bold> has been elucidated by an X‐ray structure analysis. <jats:disp-formula>
<jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" position="anchor" xlink:href="urn:x-wiley:05700833:media:ANIE198505051:nueqn001"><jats:alt-text>equation image</jats:alt-text></jats:graphic>
</jats:disp-formula></jats:p>