• Medientyp: E-Artikel
  • Titel: Inside Cover: Switching the Chirality of Single Adsorbate Complexes (Angew. Chem. Int. Ed. 22/2009)
  • Beteiligte: Parschau, Manfred; Passerone, Daniele; Rieder, Karl‐Heinz; Hug, Hans J.; Ernst, Karl‐Heinz
  • Erschienen: Wiley, 2009
  • Erschienen in: Angewandte Chemie International Edition
  • Sprache: Englisch
  • DOI: 10.1002/anie.200990112
  • ISSN: 1433-7851; 1521-3773
  • Schlagwörter: General Chemistry ; Catalysis
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  • Anmerkungen:
  • Beschreibung: <jats:title>Abstract</jats:title><jats:p><jats:bold>Wrong handedness? No problem!</jats:bold> K.‐H. Ernst et al. describe in their Communication on <jats:ext-link xmlns:xlink="http://www.w3.org/1999/xlink" ext-link-type="doi" xlink:href="10.1002/anie.200805740">page 4065 ff.</jats:ext-link> how the chirality of single adsorbates can be switched into the opposite enantiomeric state. By using inelastically tunneling electrons from the tip of a scanning tunneling microscope in an ultra‐high vacuum, certain molecular vibrations are excited that, in turn, cause different actions such as hopping, rotation, and chirality conversion at the surface.<jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/gif" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mcontent.gif"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>