Erschienen in:
Angewandte Chemie International Edition, 57 (2018) 36, Seite 11802-11806
Sprache:
Englisch
DOI:
10.1002/anie.201805526
ISSN:
1433-7851;
1521-3773
Entstehung:
Anmerkungen:
Beschreibung:
AbstractThe substrate flexibility of eight purified sesquiterpene cyclases was evaluated using six new heteroatom‐modified farnesyl pyrophosphates, and the formation of six new heteroatom‐modified macrocyclic and tricyclic sesquiterpenoids is described. GC‐O analysis revealed that tricyclic tetrahydrofuran exhibits an ethereal, peppery, and camphor‐like olfactoric scent.