Reaction of α‐cellulose with SbCl3–KOH–AsCl3

Medientyp: E-Artikel
Titel: Reaction of α‐cellulose with SbCl3–KOH–AsCl3
Beteiligte: Szymanski, Herman A.; Yelin, Robert
Erschienen: Wiley, 1967
Erschienen in: Journal of Applied Polymer Science
Sprache: Englisch
DOI: 10.1002/app.1967.070111206
ISSN: 0021-8995; 1097-4628
Schlagwörter: Materials Chemistry ; Polymers and Plastics ; Surfaces, Coatings and Films ; General Chemistry
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Beschreibung: <jats:title>Abstract</jats:title><jats:p>α‐Cellulose dissolves in a mixture of SbCl<jats:sub>3</jats:sub>, KOH, and AsCl<jats:sub>3</jats:sub>. The resulting product as identified by PMR and infrared spectroscopy is α‐<jats:sc>D</jats:sc>‐glucose. This product is unexpected, and an explanation for its formation is suggested.</jats:p>

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