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Medientyp: E-Artikel Titel: Synthesis, structure, and properties of new methacrylic derivatives of naphthalene‐2,3‐diol Beteiligte: Gawdzik, Barbara; Podkościelna, Beata; Bartnicki, Andrzej Erschienen: Wiley, 2006 Erschienen in: Journal of Applied Polymer Science, 102 (2006) 2, Seite 1886-1895 Sprache: Englisch DOI: 10.1002/app.24163 ISSN: 1097-4628; 0021-8995 Schlagwörter: Materials Chemistry ; Polymers and Plastics ; Surfaces, Coatings and Films ; General Chemistry Entstehung: Hochschulschrift: Anmerkungen: Beschreibung: <jats:title>Abstract</jats:title><jats:p>The synthesis of a new monomer, 2,3‐(2‐hydroxy‐3‐methacryloyloxypropoxy)naphthalene, and its copolymerization with divinylbenzene is presented. This monomer was obtained from naphthalene‐2,3‐diol in a two‐step synthesis. Copolymers in the form of porous microspheres were prepared by a suspension‐emulsion polymerization method. As pore‐forming diluents, toluene, 1‐decanol, benzyl alcohol, and their mixtures were used. In studies of their porous structure, two methods were used: the adsorption of nitrogen at low temperatures, which provided information about the porous structure of the material in a dry state, and inverse exclusion chromatography, which provided information about the porous structure of the polymer swollen by a good solvent. The obtained results suggest that the porous structures for the dry and swollen polymers were different. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1886–1895, 2006</jats:p>