Beschreibung:
<jats:title>Abstract</jats:title><jats:p>Air oxidation of (Oxydi‐2,1‐phenylene)(2‐phenoxyphenyl)stibane (<jats:bold>1</jats:bold>) gives the phenoxystibane oxide [(2‐PhOC<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>)O(C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>)<jats:sub>2</jats:sub>Sb]<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> (<jats:bold>2</jats:bold>). Single crystals of (<jats:italic>o</jats:italic>‐Tol<jats:sub>2</jats:sub>Sb)<jats:sub>4</jats:sub>− O<jats:sub>4</jats:sub>(O<jats:sub>2</jats:sub>)<jats:sub>2</jats:sub> (<jats:bold>3</jats:bold>) were obtained by air oxidation of <jats:italic>o</jats:italic>‐TolSb‐(SiMe<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>. Crystal structures of 2 and 3 are reported.</jats:p>