Binary Lead Fluoride Pb3F8

Medientyp: E-Artikel
Titel: Binary Lead Fluoride Pb3F8
Beteiligte: Deubner, H. Lars; Sachs, Malte; Bandemehr, Jascha; Ivlev, Sergei I.; Karttunen, Antti J.; Kachel, Stefan R.; Klein, Benedikt P.; Ruppenthal, Lukas; Schöniger, Maik; Krug, Claudio K.; Herritsch, Jan; Gottfried, J. Michael; Aman, Jamal N. M.; Schmedt auf der Günne, Jörn; Kraus, Florian
Erschienen: Wiley, 2019
Erschienen in: Chemistry – A European Journal
Sprache: Englisch
DOI: 10.1002/chem.201903954
ISSN: 0947-6539; 1521-3765
Schlagwörter: General Chemistry ; Catalysis ; Organic Chemistry
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Beschreibung: <jats:title>Abstract</jats:title><jats:p>The binary lead fluoride Pb<jats:sub>3</jats:sub>F<jats:sub>8</jats:sub> was synthesized by the reaction of anhydrous HF with Pb<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub> or by the reaction of BrF<jats:sub>3</jats:sub> with PbF<jats:sub>2</jats:sub>. The compound was characterized by single‐crystal and powder X‐ray diffraction, IR, Raman, and solid‐state MAS <jats:sup>19</jats:sup>F NMR spectroscopy, as well as thermogravimetric analysis, XP and near‐edge X‐ray absorption fine structure (NEXAFS) spectroscopy. Solid‐state quantum‐chemical calculations are provided for the vibrational analyses and band assignments. The electronic band structure offers an inside view of the mixed valence compound.</jats:p>

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