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Sorrenti, Alessandro; Altieri, Barbara; Ceccacci, Francesca; Di Profio, Pietro; Germani, Raimondo; Giansanti, Luisa; Savelli, Gianfranco; Mancini, Giovanna

Deracemization of bilirubin as the marker of the chirality of micellar aggregates

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  • Medientyp: E-Artikel
  • Titel: Deracemization of bilirubin as the marker of the chirality of micellar aggregates
  • Beteiligte: Sorrenti, Alessandro; Altieri, Barbara; Ceccacci, Francesca; Di Profio, Pietro; Germani, Raimondo; Giansanti, Luisa; Savelli, Gianfranco; Mancini, Giovanna
  • Erschienen: Wiley, 2012
  • Erschienen in: Chirality
  • Sprache: Englisch
  • DOI: 10.1002/chir.21026
  • ISSN: 0899-0042; 1520-636X
  • Schlagwörter: Organic Chemistry ; Spectroscopy ; Drug Discovery ; Pharmacology ; Catalysis ; Analytical Chemistry
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  • Beschreibung: <jats:title>Abstract</jats:title><jats:p>The deracemization of bilirubin in micellar aggregates of structurally correlated chiral surfactants was studied by circular dichroism experiments and exploited as the marker of the expression of chirality of the aggregates. The obtained results suggest that the hydrophobic interactions control the transfer of chirality from the monomers to the aggregates, and that different regions of the same aggregate might feature opposite enantiorecognition capabilities. Chirality, 2011. © 2011 Wiley Periodicals, Inc.</jats:p>