• Medientyp: E-Artikel
  • Titel: A Robust, Broadly Absorbing Fulgide Derivative as a Universal Chemical Actinometer for the UV to NIR Region
  • Beteiligte: Reinfelds, Matiss; Hermanns, Volker; Halbritter, Thomas; Wachtveitl, Josef; Braun, Markus; Slanina, Tomáš; Heckel, Alexander
  • Erschienen: Wiley, 2019
  • Erschienen in: ChemPhotoChem
  • Sprache: Englisch
  • DOI: 10.1002/cptc.201900010
  • ISSN: 2367-0932
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  • Beschreibung: <jats:title>Abstract</jats:title><jats:p>A fulgide photoswitch is presented as a novel actinometer for a broad range of wavelengths from the UV to the NIR region (340–700 nm). It is easily accessible and has a robust photochemistry and high fatigue resistance. Its photophysics and photochemistry are described in detail. Quantum yields of photoswitching were measured for a series of wavelengths and standardized against known standards (ferrioxalate actinometry, calibrated photodiode). We also present a method for the precise determination of photoswitching quantum yields by global analysis of the whole spectra and an alternative quick and easy method for rapid determination of photon fluxes.</jats:p>