2,3‐Di‐n‐undecylanthracene and 2,3‐Di‐n‐decyloxyanthracene (DDOA) – on the Connecting Link between t… - SLUB Dresden

Medientyp: E-Artikel
Titel: 2,3‐Di‐n‐undecylanthracene and 2,3‐Di‐n‐decyloxyanthracene (DDOA) – on the Connecting Link between the Aromatic Substrate and the Aliphatic Chain in Self‐Assembling Systems
Beteiligte: Hopf, Henning; Greiving, Helmut; Bouas‐Laurent, Henri; Desvergne, Jean‐Pierre
Erschienen: Wiley, 2009
Erschienen in: European Journal of Organic Chemistry, 2009 (2009) 12, Seite 1868-1870
Sprache: Englisch
DOI: 10.1002/ejoc.200801156
ISSN: 1434-193X; 1099-0690
Schlagwörter: Organic Chemistry ; Physical and Theoretical Chemistry
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Beschreibung: <jats:title>Abstract</jats:title><jats:p>In contrast to its bis(oxa) analog <jats:bold>1</jats:bold> (DDOA), the hydrocarbon <jats:bold>11</jats:bold> was not found to form organogels with linear alcohols, alkanes, toluene, acetonitrile and other solvents. Whereas the photoreactivity of <jats:bold>1</jats:bold> did not follow the usual behaviour of anthracene derivatives, compound <jats:bold>11</jats:bold>, irradiated in cyclohexane, produced the two expected [4+4]cycloadducts <jats:bold>12</jats:bold> and <jats:bold>13</jats:bold> (<jats:italic>anti</jats:italic> and <jats:italic>syn</jats:italic> photodimers, respectively). These facts point to the role of the connecting link between the rigid core and the flexible chain for some self‐assembled systems.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)</jats:p>

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