Beschreibung:
A pathway to access 11‐substituted 11H‐indolo[3,2‐c]quinolines is described. The protocol features a chemoselective Suzuki reaction of o‐dihaloquinolines with o‐bromophenylboronic acid, followed by double C–N coupling with primary amines. The molecular structure of a representative product is exemplified, and demonstrates well‐defined π‐stacking interactions in the molecular network.