Erschienen in:
European Journal of Organic Chemistry, 26 (2023) 1
Sprache:
Englisch
DOI:
10.1002/ejoc.202201114
ISSN:
1434-193X;
1099-0690
Entstehung:
Anmerkungen:
Beschreibung:
AbstractDual catalysis is one of the most powerful strategies for the development of chemical reactions in organic synthesis. This strategy can be divided into cooperative catalysis, relay catalysis, and sequential catalysis according to the actual mode of operation and the communication between the catalysts. In recent years, such strategy has been applied in a large number of studies since it has the advantages of: 1) increasing reactivity and enabling challenging transformations; 2) offering a powerful way of controlling the stereoselectivity of asymmetric reactions, which is challenging for traditional catalytic systems; 3) catalyze the stereodivergent synthesis of molecules bearing one or more stereocenters from the same starting materials. This Perspective, which intends to introduce the reader toEurJOC special collection on Dual Catalysis, aims to summarize and introduce the different categories of dual catalysis and demonstrate their benefits in constructing new chemical bonds in a selective manner. Finally, current challenges and new trends in dual catalysis will be also presented.