Beschreibung:
<jats:title>Abstract</jats:title><jats:p>A nucleophilic substitution reaction in the pyrrole series, achieved by a neutral nucleophile, led to the key intermediate <jats:bold>7</jats:bold> which by reduction and successive diazotization afforded the new ring system pyrrolo[3,2‐<jats:italic>c</jats:italic>][1,2,5]benzotriazocine <jats:bold>9</jats:bold> in good yield.</jats:p>