Klais, Odo;
Anderson, Philip C.;
Kurylo, Michael J.
A reinvestigation of the temperature dependence of the rate constant for the reaction O + O2+ M → O3+ M (for M = O2, N2, and Ar) by the flash photolysis resonance fluorescence technique
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Medientyp:
E-Artikel
Titel:
A reinvestigation of the temperature dependence of the rate constant for the reaction O + O2+ M → O3+ M (for M = O2, N2, and Ar) by the flash photolysis resonance fluorescence technique
Beteiligte:
Klais, Odo;
Anderson, Philip C.;
Kurylo, Michael J.
Erschienen:
Wiley, 1980
Erschienen in:
International Journal of Chemical Kinetics, 12 (1980) 7, Seite 469-490
Beschreibung:
<jats:title>Abstract</jats:title><jats:p>The flash photolysis resonance fluorescence technique has been used to reinvestigate the kinetics of the oxygen atom–oxygen molecule combination reaction. Third‐order rate constants for O<jats:sub>2</jats:sub>, N<jats:sub>2</jats:sub>, and Ar as deactivant molecules were determined over the temperature range of 219–368 K. The results presented herein are the most extensive data sets available for atmospheric modeling and are used to formulate a recommendation for such purposes. The recommended rate expressions are<jats:disp-formula />or<jats:disp-formula />Comparisons of these results with existing literature data are presented.</jats:p>