• Medientyp: E-Artikel
  • Titel: Rate‐effect on fracture behavior of core‐shell‐rubber (CSR)‐modified epoxies
  • Beteiligte: Xiao, Keqin; Ye, Lin
  • Erschienen: Wiley, 2000
  • Erschienen in: Polymer Engineering & Science
  • Sprache: Englisch
  • DOI: 10.1002/pen.11140
  • ISSN: 0032-3888; 1548-2634
  • Schlagwörter: Materials Chemistry ; Polymers and Plastics ; General Chemistry ; Materials Chemistry ; Polymers and Plastics ; General Chemistry
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  • Beschreibung: <jats:title>Abstract</jats:title><jats:p>A bisphenol A diglycidylether (DGEBA) epoxy was modified with up to 20 wt% of a core‐shell rubber (CSR), and mechanical properties were investigated at different crosshead rates (from 0.5 mm/min to 500 mm/min). The yield strength and Young's modulus decreased almost linearly with increasing rubber content or decreasing crosshead rate. Fracture toughness, K<jats:sub>IC</jats:sub>, was significantly improved by the addition of CSR to the pure epoxy. The optimum rubber content was between 15% and 20% at the lowest crosshead rate (i.e. 0.5 mm/min) and shifted to higher rubber content at higher crosshead rates. K<jats:sub>IC</jats:sub> decreased slightly as the crosshead rate was increased from 0.5 mm/min and dropped significantly when the crosshead rate approached 500 mm/min. Rubber cavitation‐induced local plastic deformation was identified as the principal energy absorption mechanism, and it was independent of rubber content and crosshead rate. The variation of K<jats:sub>IC</jats:sub> with rubber content and crosshead rate correlated well with the length of the stress‐whitened zone.</jats:p>