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Medientyp: E-Artikel Titel: New fluorinated polysiloxanes containing an ester function in the spacer. I. Synthesis and characterization Beteiligte: Beyou, Emmanuel; Babin, Pierre; Bennetau, Bernard; Dunogues, Jacques; Teyssie, Dominique; Boileau, Sylvie Erschienen: Wiley, 1994 Erschienen in: Journal of Polymer Science Part A: Polymer Chemistry, 32 (1994) 9, Seite 1673-1681 Sprache: Englisch DOI: 10.1002/pola.1994.080320909 ISSN: 1099-0518; 0887-624X Schlagwörter: Materials Chemistry ; Organic Chemistry ; Polymers and Plastics Entstehung: Anmerkungen: Beschreibung: AbstractUnsaturated perfluoroalkyl esters derived from undecylenic acid: CH2CH(CH2)8COOCH2CH2RF (with RFC6F13, 2a and RFC8F17, 2b) and C8F17(CH2)10COOCH2CHCH2, 2c were prepared with excellent yields. Their hydrosilylation by methylhydrodimethylsiloxane copolymers of various SiH contents gives new fluorinated polysiloxanes which were examined by 1H‐ and 13C‐NMR, GPC, differential scanning calorimetry, and optical polarizing microscopy. Polymers derived from compounds 2a and 2b exhibit mesomorphic structures. © 1994 John Wiley & Sons, Inc.