• Medientyp: E-Artikel
  • Titel: New fluorinated polysiloxanes containing an ester function in the spacer. I. Synthesis and characterization
  • Beteiligte: Beyou, Emmanuel; Babin, Pierre; Bennetau, Bernard; Dunogues, Jacques; Teyssie, Dominique; Boileau, Sylvie
  • Erschienen: Wiley, 1994
  • Erschienen in: Journal of Polymer Science Part A: Polymer Chemistry, 32 (1994) 9, Seite 1673-1681
  • Sprache: Englisch
  • DOI: 10.1002/pola.1994.080320909
  • ISSN: 1099-0518; 0887-624X
  • Schlagwörter: Materials Chemistry ; Organic Chemistry ; Polymers and Plastics
  • Entstehung:
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  • Beschreibung: AbstractUnsaturated perfluoroalkyl esters derived from undecylenic acid: CH2CH(CH2)8COOCH2CH2RF (with RFC6F13, 2a and RFC8F17, 2b) and C8F17(CH2)10COOCH2CHCH2, 2c were prepared with excellent yields. Their hydrosilylation by methylhydrodimethylsiloxane copolymers of various SiH contents gives new fluorinated polysiloxanes which were examined by 1H‐ and 13C‐NMR, GPC, differential scanning calorimetry, and optical polarizing microscopy. Polymers derived from compounds 2a and 2b exhibit mesomorphic structures. © 1994 John Wiley & Sons, Inc.