• Medientyp: E-Artikel
  • Titel: Half‐Heusler superlattices as model systems for nanostructured thermoelectrics
  • Beteiligte: Komar, Paulina; Jaeger, Tino; Euler, Christoph; Chávez Angel, Emigdio; Kolb, Ute; Müller, Mathis M.; Balke, Benjamin; Aguirre, Myriam Haydee; Populoh, Sascha; Weidenkaff, Anke; Jakob, Gerhard
  • Erschienen: Wiley, 2016
  • Erschienen in: physica status solidi (a), 213 (2016) 3, Seite 732-738
  • Sprache: Englisch
  • DOI: 10.1002/pssa.201532445
  • ISSN: 1862-6300; 1862-6319
  • Schlagwörter: Materials Chemistry ; Electrical and Electronic Engineering ; Surfaces, Coatings and Films ; Surfaces and Interfaces ; Condensed Matter Physics ; Electronic, Optical and Magnetic Materials
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  • Beschreibung: <jats:title>Abstract</jats:title><jats:sec><jats:label /><jats:p>The efficiency of thermoelectric materials is directly related to the dimensionless figure of merit <jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/pssa201532445-math-0001.png" xlink:title="urn:x-wiley::media:pssa201532445:pssa201532445-math-0001" />, therefore, one of the means to improve <jats:italic>ZT</jats:italic> is to reduce the thermal conductivity. Our research focuses on half‐Heusler superlattices (SLs) and the relationship between the SL period and the thermal conductivity. The cross‐plane thermal conductivity of DC‐sputtered TiNiSn/HfNiSn SLs was measured by the 3<jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/pssa201532445-math-0002.png" xlink:title="urn:x-wiley::media:pssa201532445:pssa201532445-math-0002" /> method at room temperature and a clear reduction of <jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/pssa201532445-math-0003.png" xlink:title="urn:x-wiley::media:pssa201532445:pssa201532445-math-0003" /> was achieved for all SL periods, in particular for periods smaller than 20 nm. Moreover, the thermal conductivities of TiNiSn and HfNiSn single films display reduced values compared to the literature data for bulk materials. Furthermore, we also found that the quality of interfaces has an influence on <jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/pssa201532445-math-0004.png" xlink:title="urn:x-wiley::media:pssa201532445:pssa201532445-math-0004" />, namely, SLs with rougher interfaces exhibit an about 20% lower thermal conductivity compared to samples with sharp interfaces.</jats:p></jats:sec>