• Medientyp: E-Artikel
  • Titel: Prediction of thermodynamic properties: centerpiece approach—how do we avoid confusion and get reliable results?
  • Beteiligte: Verevkin, Sergey P.; Andreeva, Irina V.; Zherikova, Kseniya V.; Pimerzin, Aleksey A.
  • Erschienen: Springer Science and Business Media LLC, 2022
  • Erschienen in: Journal of Thermal Analysis and Calorimetry, 147 (2022) 15, Seite 8525-8534
  • Sprache: Englisch
  • DOI: 10.1007/s10973-021-11115-4
  • ISSN: 1388-6150; 1588-2926
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  • Beschreibung: <jats:title>Abstract</jats:title><jats:p>The absolute vapor pressures of three amino-alcohols were measured using the transpiration method. The consistent set of standard molar enthalpies of vaporization for eighteen amino-alcohols was evaluated using empirical and structure–property correlations. The averaged values of vaporization enthalpies were recommended as reliable benchmark properties for the heat management of CO<jats:sub>2</jats:sub> capture technologies. Centerpiece approach based on the group-additivity principles was developed toward amino-alcohols.</jats:p> <jats:p><jats:bold>Graphic abstract</jats:bold></jats:p>