• Medientyp: E-Artikel
  • Titel: Chelated [Zn(cyclam)]2+Lewis acid improves the reactivity of the electrochemical reduction of CO2by Mn catalysts with bulky bipyridine ligands
  • Beteiligte: Zhanaidarova, Almagul; Steger, Han; Reineke, Mark H.; Kubiak, Clifford. P.
  • Erschienen: Royal Society of Chemistry (RSC), 2017
  • Erschienen in: Dalton Transactions
  • Sprache: Englisch
  • DOI: 10.1039/c7dt02620j
  • ISSN: 1477-9226; 1477-9234
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  • Beschreibung: <p>This communication reports the use of a soluble Lewis acid complex, [Zn(cyclam)]<sup>2+</sup>(cyclam = 1,4,8,11-tetraazacyclotetradecane) as a co-catalyst coupled with Mn(Mesbpy)(CO)<sub>3</sub>Br (Mesbpy = 6,6′-dimesityl-2,2′-bipyridine) for the electrochemical reduction of CO<sub>2</sub>to CO.</p>