• Medientyp: E-Artikel
  • Titel: A long-lived fluorenyl cation: efficiency booster for uncaging and photobase properties
  • Beteiligte: Abdellaoui, Chahinez; Hermanns, Volker; Reinfelds, Matiss; Scheurer, Maximilian; Dreuw, Andreas; Heckel, Alexander; Wachtveitl, Josef
  • Erschienen: Royal Society of Chemistry (RSC), 2022
  • Erschienen in: Physical Chemistry Chemical Physics
  • Sprache: Englisch
  • DOI: 10.1039/d1cp05292f
  • ISSN: 1463-9084; 1463-9076
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  • Beschreibung: <jats:p>The symmetric dimethylamino-fluorene proved to be a more efficient photolabile protecting group than non-symmetric analogue. This is due to the long-lived fluorenyl cation intermediate, which also enables application as hydroxide emitting photobase.</jats:p>