• Medientyp: E-Artikel
  • Titel: Degradation kinetics of polyimide film
  • Beteiligte: Hondred, Peter R.; Yoon, Sungho; Bowler, Nicola; Moukhina, Elena; Kessler, Michael R.
  • Erschienen: SAGE Publications, 2011
  • Erschienen in: High Performance Polymers
  • Sprache: Englisch
  • DOI: 10.1177/0954008311409262
  • ISSN: 0954-0083; 1361-6412
  • Schlagwörter: Materials Chemistry ; Organic Chemistry ; Polymers and Plastics
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  • Beschreibung: <jats:p> Through the use of thermogravimetry (TG), this work explores the thermal degradation mechanism and kinetics of Kapton (polyimide) film. Isoconversional kinetic methods, which provide activation energy as a function of degradation, present insight into the development of a five-step competitive and consecutive kinetic model. To evaluate the accuracy and validity of the model, a statistical analysis of the implemented kinetic model is also presented. Coupled TG-mass spectroscopy and TG-Fourier transform infrared analysis were used to investigate the decomposition mechanism and to more fully explain the complex, heating-rate-dependent, decomposition pathway of Kapton. </jats:p>