• Medientyp: E-Artikel
  • Titel: Nuclear Magnetic Resonance Study of Exchanging Systems. IX. The Slow Rotation of the Methyl Group in Sterically Overcrowded Compounds
  • Beteiligte: Nakanishi, Hiroshi; Yamamoto, Osamu
  • Erschienen: Oxford University Press (OUP), 1977
  • Erschienen in: Bulletin of the Chemical Society of Japan
  • Sprache: Englisch
  • DOI: 10.1246/bcsj.50.3018
  • ISSN: 0009-2673; 1348-0634
  • Schlagwörter: General Chemistry
  • Entstehung:
  • Anmerkungen:
  • Beschreibung: <jats:title>Abstract</jats:title> <jats:p>In order to obtain information about the slow rotation of methyl groups, the 1H NMR spectra of 9-t-butylethenoanthracene and 9-t-butyltriptycene derivatives were measured at very low temperatures. It was found that the signals of the two methyls of the t-butyl group in these compounds show a considerable line broadening at low temperatures, and it was made clear that the rotation of the methyl groups in these compounds is strongly restricted.</jats:p>
  • Zugangsstatus: Freier Zugang