Beschreibung:
A reinvestigation of the nitrogen-14 NQR in thiourea has permitted to record, apparently for the first time, the resonances above 169 K. The first order and second order of the transitions at 169 K and 202 K, respectively, appear clearly from the temperature dependence of the resonance frequencies; the modulated structure, incommensurate or commensurate, is also seen on the 14N NQR spectrum. This study is the first step of a new investigation of thiourea and its inclusion compounds.