Design and Fabrication of New Ti-Based Ternary Metallic Glasses Based on Effective Atomic Radius in the Ti Solid Solution Calculated by Ab Initio Calculation
Sie können Bookmarks mittels Listen verwalten, loggen Sie sich dafür bitte in Ihr SLUB Benutzerkonto ein.
Medientyp:
E-Artikel
Titel:
Design and Fabrication of New Ti-Based Ternary Metallic Glasses Based on Effective Atomic Radius in the Ti Solid Solution Calculated by Ab Initio Calculation
Beschreibung:
<jats:p>New Ti-based ternary metallic glasses were designed and fabricated. A new parameter called effective atomic radius in the Ti solid solution from ab-initio calculation was used to design of the Ti-based metallic glasses. From the effective atomic radius, Ti-Zr-Mn, Ti-Zr-Fe and Ti-Zr-Co systems can be considered as a new Ti-based ternary metallic glass. And the reported scheme based on the concept of binary eutectic clusters is applied to predict alloy composition which shows glass transition.We prepared the Ti<jats:sub>4</jats:sub><jats:sub>2</jats:sub>Zr<jats:sub>22</jats:sub>Mn<jats:sub>3</jats:sub><jats:sub>6</jats:sub>, Ti<jats:sub>4</jats:sub><jats:sub>3</jats:sub>Zr<jats:sub>29</jats:sub>Fe<jats:sub>28</jats:sub> and Ti<jats:sub>4</jats:sub><jats:sub>4</jats:sub>Zr<jats:sub>30</jats:sub>Co<jats:sub>26</jats:sub> alloy sheets by a single-roller method. It showed that sharp diffraction peak corresponding to crystalline phases could be observed in the XRD spectra of Ti<jats:sub>4</jats:sub><jats:sub>2</jats:sub>Zr<jats:sub>22</jats:sub>Mn<jats:sub>3</jats:sub><jats:sub>6</jats:sub> and Ti<jats:sub>4</jats:sub><jats:sub>3</jats:sub>Zr<jats:sub>29</jats:sub>Fe<jats:sub>28</jats:sub>. While for alloy with Ti<jats:sub>4</jats:sub><jats:sub>4</jats:sub>Zr<jats:sub>30</jats:sub>Co<jats:sub>26</jats:sub> no sharp diffraction peak could be found except broad diffraction halos. This result suggests that a critical eutectic temperature in the phase equilibrium for forming glass phase is around 1000°C.</jats:p>