• Medientyp: E-Artikel
  • Titel: Mechanothermal Synthesis of SrSnO3
  • Beteiligte: Berbenni, Vittorio; Milanese, Chiara; Bruni, Giovanna; Girella, Alessandro; Marini, Amedeo
  • Erschienen: Walter de Gruyter GmbH, 2014
  • Erschienen in: Zeitschrift für Naturforschung B
  • Sprache: Englisch
  • DOI: 10.5560/znb.2014-3306
  • ISSN: 0932-0776; 1865-7117
  • Schlagwörter: General Chemistry
  • Entstehung:
  • Anmerkungen:
  • Beschreibung: <jats:p>The synthesis of strontium metastannate (SrSnO<jats:sub>3</jats:sub>) has been performed by coupling mechanical activation with thermal activation of SnC<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>-SrCO<jats:sub>3</jats:sub> mixtures. The solid-state reaction has been studied by TG-DSC analysis and powder X-ray diffraction. By annealing experiments performed on physical mixtures (no mechanical activation) it has been assessed that the formation of SrSnO<jats:sub>3</jats:sub> occurs through the intermediate Sr<jats:sub>2</jats:sub>SnO<jats:sub>4</jats:sub> and is complete only after annealing at 1400 °C. By performing the annealing experiments on activated mixtures it has been established that the formation of SrSnO<jats:sub>3</jats:sub> takes place directly at temperatures between 800 and 1000 °C. The SrSnO<jats:sub>3</jats:sub> samples obtained at 800 and 900 °C show, by TG analysis, mass loss processes that suggest that SrSnO<jats:sub>3</jats:sub> obtained at these temperatures absorbs H<jats:sub>2</jats:sub>O and CO<jats:sub>2</jats:sub> from the air so that its use as gas sensor can be envisaged. This is no longer true for the sample obtained at 1000 °C or above </jats:p>
  • Zugangsstatus: Freier Zugang