• Medientyp: E-Artikel
  • Titel: [2 + 2] Photocycloadditions in the Synthesis of Chiral Molecules
  • Beteiligte: Schreiber, Stuart L.
  • Erschienen: The American Association for the Advancement of Science, 1985
  • Erschienen in: Science, 227 (1985) 4689, Seite 857-863
  • Sprache: Englisch
  • ISSN: 0036-8075; 1095-9203
  • Schlagwörter: Chemistry
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  • Anmerkungen:
  • Beschreibung: <p>A strategy for the synthesis of chiral molecules that receives growing popularity among organic chemists employs the photochemically mediated [2 + 2] cycloaddition reaction. These reactions can be performed on a multigram scale and often proceed with high yield and with stereocontrol. These features, in combination with the useful properties of the four-membered ring photoproducts in subsequent chemical transformations, make them attractive options in the early stage of a synthesis design. Various combinations of unsaturated functional groups can participate in this reaction process. Accordingly, these chemical reactions can be economical solutions to problems relating to the synthesis of a variety of target molecules.</p>