• Media type: E-Article
  • Title: On the preponderance of near-prolate rotors among polyatomic molecules
  • Contributor: Silbey, Robert J.; Kinsey, James L.
  • Published: AIP Publishing, 1988
  • Published in: The Journal of Chemical Physics, 88 (1988) 6, Seite 4100-4100
  • Language: English
  • DOI: 10.1063/1.453815
  • ISSN: 0021-9606; 1089-7690
  • Keywords: Physical and Theoretical Chemistry ; General Physics and Astronomy
  • Origination:
  • Footnote:
  • Description: <jats:p>The distribution with respect to Ray’s asymmetry parameter κ of polyatomic molecules listed in the Landolt–Börstein tables is skewed towards κ=−1 (prolate rotor limit). A plausible definition of ‘‘randomly shaped’’ objects leads to a prediction with this qualitative behavior but less strongly biased toward κ=−1 than the experimental distribution.</jats:p>