• Medientyp: E-Artikel
  • Titel: On the preponderance of near-prolate rotors among polyatomic molecules
  • Beteiligte: Silbey, Robert J.; Kinsey, James L.
  • Erschienen: AIP Publishing, 1988
  • Erschienen in: The Journal of Chemical Physics, 88 (1988) 6, Seite 4100-4100
  • Sprache: Englisch
  • DOI: 10.1063/1.453815
  • ISSN: 0021-9606; 1089-7690
  • Schlagwörter: Physical and Theoretical Chemistry ; General Physics and Astronomy
  • Entstehung:
  • Anmerkungen:
  • Beschreibung: <jats:p>The distribution with respect to Ray’s asymmetry parameter κ of polyatomic molecules listed in the Landolt–Börstein tables is skewed towards κ=−1 (prolate rotor limit). A plausible definition of ‘‘randomly shaped’’ objects leads to a prediction with this qualitative behavior but less strongly biased toward κ=−1 than the experimental distribution.</jats:p>