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Cao, Haoying; Ma, Shanshan; Feng, Yanhong; Guo, Yawen; Jiao, Peng

Synthesis of β-nitro ketones from geminal bromonitroalkanes and silyl enol ethers by visible light photoredox catalysis

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  • Media type: E-Article
  • Title: Synthesis of β-nitro ketones from geminal bromonitroalkanes and silyl enol ethers by visible light photoredox catalysis
  • Contributor: Cao, Haoying; Ma, Shanshan; Feng, Yanhong; Guo, Yawen; Jiao, Peng
  • imprint: Royal Society of Chemistry (RSC), 2022
  • Published in: Chemical Communications
  • Language: English
  • DOI: 10.1039/d1cc06529g
  • ISSN: 1359-7345; 1364-548X
  • Origination:
  • Footnote:
  • Description: <jats:p>Photocatalytic coupling reaction between a TMS enol ether and a <jats:italic>gem</jats:italic>-bromonitroalkane furnishes a ketone bearing β-NO<jats:sub>2</jats:sub> group on a tertiary carbon, which is easily converted into a β-NH<jats:sub>2</jats:sub> ketone. α-Nitro radicals are intermediates.</jats:p>