Erschienen:
Royal Society of Chemistry (RSC), 2022
Erschienen in:Chemical Communications
Sprache:
Englisch
DOI:
10.1039/d1cc06529g
ISSN:
1359-7345;
1364-548X
Entstehung:
Anmerkungen:
Beschreibung:
<jats:p>Photocatalytic coupling reaction between a TMS enol ether and a <jats:italic>gem</jats:italic>-bromonitroalkane furnishes a ketone bearing β-NO<jats:sub>2</jats:sub> group on a tertiary carbon, which is easily converted into a β-NH<jats:sub>2</jats:sub> ketone. α-Nitro radicals are intermediates.</jats:p>