Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese complexes throughout redox cycling
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Media type:
E-Article
Title:
Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese complexes throughout redox cycling
Published in:
Chemical Science, 12 (2021) 31, Seite 10483-10500
Language:
English
DOI:
10.1039/d1sc02465e
ISSN:
2041-6520;
2041-6539
Origination:
Footnote:
Description:
Manganese complexes with polydentate quinol-containing ligands are found to catalyze the degradation of superoxide through inner-sphere mechanisms. The redox activity of the ligand stabilizes higher-valent manganese species.