Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese complexes throughout redox cycling
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Medientyp:
E-Artikel
Titel:
Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese complexes throughout redox cycling
Erschienen:
Royal Society of Chemistry (RSC), 2021
Erschienen in:
Chemical Science, 12 (2021) 31, Seite 10483-10500
Sprache:
Englisch
DOI:
10.1039/d1sc02465e
ISSN:
2041-6520;
2041-6539
Entstehung:
Anmerkungen:
Beschreibung:
Manganese complexes with polydentate quinol-containing ligands are found to catalyze the degradation of superoxide through inner-sphere mechanisms. The redox activity of the ligand stabilizes higher-valent manganese species.